Chemical element · Atomic number 33

Arsenic

Arsenic in the periodic table: atomic number 33, electron configuration, atomic mass, physical data, oxidation states, media credit and visible sources.

As

Metalloid

solid

74.92159 u

Silvery-gray sample of elemental arsenic from an element collectionDocumented element sample

A documented sample of elemental arsenic, a brittle metalloid.

Image credit: James St. John

Auto-oriented, limited to 1600 × 1200 pixels and re-encoded as WebP; the subject was not altered.

Commons fileLicence: CC BY 2.0

Atomic classification

Arsenic in the Bohr shell modelThis shows the electron distribution of the neutral atom in a simplified shell model.: 2 · 8 · 18 · 5

Shell occupancy

Arsenic in the Bohr shell model

This shows the electron distribution of the neutral atom in a simplified shell model.

K · n=1
2 electrons
L · n=2
8 electrons
M · n=3
18 electrons
N · n=4
5 electrons
Shell occupancy is derived from the versioned PubChem electron configuration. Dot angles are schematic and do not represent orbitals.
Electron configuration
[Ar]4s2 3d10 4p3
Electrons per shell
2 · 8 · 18 · 5
Group
15
Period
4
Block
P
Element category
Metalloid

Physical and chemical properties

Atomic mass
74.92159 u
Standard state
solid
Density
5.776 g/cm³
Melting point
1,090 K
Boiling point
887 K
Electronegativity
2.18 (Pauling)
First ionisation energy
9.815 eV
Oxidation states
+5, +3, -3
Discovery
known since antiquity

Safety and periodic classification

Safety

Safe handling cannot be inferred from Arsenic's position in the periodic table alone. Laboratory, classroom and disposal decisions must follow the documentation for the exact material and its safety data sheet.

Position and comparison

Arsenic is in period 4, group 15 and the P block. Its direct neighbours by atomic number are Germanium and Selenium. The recorded Pauling electronegativity is 2.18. Periodic trends are compared only through the separately sourced neighbouring values.

Sources and scope

PubChem attributes element data to sources including IUPAC, NIST and IAEA. Quanta stores the referenced snapshot locally and leaves unknown values unavailable.

Where Arsenic sits among the 118 elements

The table compares the reported values for Arsenic with every other element that carries the same value in the snapshot. A rank is not a judgement, it is orientation: it says how unusual this value is across the periodic table.

ValueArsenicPosition in the data set
Melting point1,090 KRank 60 of 103 elements with a reported value. Highest: Carbon.
Boiling point887 KRank 77 of 93 elements with a reported value. Highest: Rhenium.
Density5.776 g/cm³Rank 60 of 96 elements with a reported value. Highest: Osmium.
Electronegativity (Pauling)2.18Rank 24 of 95 elements with a reported value. Highest: Fluorine.
Ionisation energy9.815 eVRank 18 of 102 elements with a reported value. Highest: Helium.

All values and ranks come from the PubChem Periodic Table snapshot, retrieved on 2026-07-15. Elements without a reported value are excluded, so the population differs per row.

The neighbours of Arsenic in the periodic table

Place in the table
Group 15, period 4, P block. Classified as metalloid, solid at standard conditions.
Direct neighbours
Atomic number 33. Preceded by Germanium, followed by Selenium.
Same group
Same number of outer electrons, and therefore similar reactivity to Nitrogen, Phosphorus, Antimony, Bismuth, Moscovium.
Discovery
Recorded in the snapshot as: known since antiquity. Who, where and under what circumstances is not part of that record, so this page carries the sourced year and no discovery narrative.
Oxidation states
+5, +3, -3. They follow from the electron configuration [Ar]4s2 3d10 4p3 and indicate which compounds to expect.

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