Chemical element · Atomic number 3

Lithium

Lithium in the periodic table: atomic number 3, electron configuration, atomic mass, physical data, oxidation states, media credit and visible sources.

Li

Alkali metal

solid

7.0 u

Freshly cut piece of metallic lithium with a bright cut surface and areas that have already tarnishedDocumented element sample

A freshly cut lithium sample; a dull surface layer forms quickly in air.

Image credit: Dnn87

Auto-oriented, limited to 1600 × 1200 pixels and re-encoded as WebP; the subject was not altered.

Commons fileLicence: CC BY 3.0

Atomic classification

Lithium in the Bohr shell modelThis shows the electron distribution of the neutral atom in a simplified shell model.: 2 · 1

Shell occupancy

Lithium in the Bohr shell model

This shows the electron distribution of the neutral atom in a simplified shell model.

K · n=1
2 electrons
L · n=2
1 electron
Shell occupancy is derived from the versioned PubChem electron configuration. Dot angles are schematic and do not represent orbitals.
Electron configuration
[He]2s1
Electrons per shell
2 · 1
Group
1
Period
2
Block
S
Element category
Alkali metal

Physical and chemical properties

Atomic mass
7.0 u
Standard state
solid
Density
0.534 g/cm³
Melting point
453.65 K
Boiling point
1,615 K
Electronegativity
0.98 (Pauling)
First ionisation energy
5.392 eV
Oxidation states
+1
Discovery
1817

Safety and periodic classification

Safety

Safe handling cannot be inferred from Lithium's position in the periodic table alone. Laboratory, classroom and disposal decisions must follow the documentation for the exact material and its safety data sheet.

Position and comparison

Lithium is in period 2, group 1 and the S block. Its direct neighbours by atomic number are Helium and Beryllium. The recorded Pauling electronegativity is 0.98. Periodic trends are compared only through the separately sourced neighbouring values.

Sources and scope

PubChem attributes element data to sources including IUPAC, NIST and IAEA. Quanta stores the referenced snapshot locally and leaves unknown values unavailable.

Where Lithium sits among the 118 elements

The table compares the reported values for Lithium with every other element that carries the same value in the snapshot. A rank is not a judgement, it is orientation: it says how unusual this value is across the periodic table.

ValueLithiumPosition in the data set
Melting point453.65 KRank 80 of 103 elements with a reported value. Highest: Carbon.
Boiling point1,615 KRank 64 of 93 elements with a reported value. Highest: Rhenium.
Density0.534 g/cm³Rank 85 of 96 elements with a reported value. Highest: Osmium.
Electronegativity (Pauling)0.98Rank 87 of 95 elements with a reported value. Highest: Fluorine.
Ionisation energy5.392 eVRank 94 of 102 elements with a reported value. Highest: Helium.

All values and ranks come from the PubChem Periodic Table snapshot, retrieved on 2026-07-15. Elements without a reported value are excluded, so the population differs per row.

The neighbours of Lithium in the periodic table

Place in the table
Group 1, period 2, S block. Classified as alkali metal, solid at standard conditions.
Direct neighbours
Atomic number 3. Preceded by Helium, followed by Beryllium.
Same group
Same number of outer electrons, and therefore similar reactivity to Hydrogen, Sodium, Potassium, Rubidium, Cesium, Francium.
Discovery
Recorded in the snapshot as: 1817. Who, where and under what circumstances is not part of that record, so this page carries the sourced year and no discovery narrative.
Oxidation states
+1. They follow from the electron configuration [He]2s1 and indicate which compounds to expect.

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